Biden became the 47th Vice President of the United States in 2009 and is currently serving his second term with President Barack Obama. Previously, he served 36 years as a U.S. Senator from Delaware.

Biden will join the previously announced guests Uber CEO Travis Kalanick and country singer Toby Keith.  

THE LATE SHOW with STEPHEN COLBERT, a production of The Late Show Inc., premieres Tuesday, Sept. 8 (11:35 PM-12:37 AM, ET/PT) on the CBS Television Network.  Stephen Colbert, Tom Purcell and Meredith Bennett are the executive producers.  

CHEAT TWEET: JUST IN! @VP #JoeBiden sits down w/ @StephenAtHome on @ColbertLateShow Thurs. 9/10, 11:35pm #LSSC #CBS! http://bit.ly/1NVeyuo

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